Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel

Nanocasting was used to develop epoxy/graphene composites (EGCs) as corrosion inhibitors with hydrophobic surfaces (HEGC). The contact angle of water droplets on a sample surface can be increased from -82 (epoxy surface) to -127 (hydrophobic epoxy and EGC). It should be noted that EGC coating was found to provide an excellent corrosion protection effect on cold-rolled steel (CRS) electrode. Enhancement of corrosion protection using EGC coatings could be attributed to the following three reasons: (1) epoxy could act as a physical barrier coating, (2) the hydrophobicity repelled the moisture and further reduced the water/corrosive media adsorption on the epoxy surface, preventing the underlying metals from corrosion attack, and (3) the well-dispersed graphene nanosheets (GNSs) embedded in HEGC matrix could prevent corrosion owing to a relatively higher aspect ratio than clay platelets, which enhances the oxygen barrier property of HEGC. (C) 2013 Elsevier Ltd. All rights reserved.