期刊
CARBON
卷 55, 期 -, 页码 328-334出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2012.12.072
关键词
-
资金
- Natural Science Foundation of China [50825203, 21175050]
- 863 program [2011AA11290]
- PCSIRT (Program for Changjiang Scholars and Innovative Research Team in University)
The electrochemical performance of sodium-ion battery was improved by using functionalized interconnected N-doped carbon nanofibers (FN-CNFs) as the anode. The material was synthesized with polypyrrole as precursor by a simple method. The FN-CNF electrode exhibits excellent rate capability and cycling stability, delivering a capacity of 134.2 mAh g(-1) at a high current density of 200 mA g(-1) after 200 cycles and retains a capacity of 73 mAh g(-1) even at an extremely high current density of 20 A g(-1). The superior performance can be attributed to N-doped sites and functionalized groups, which are capable of capturing sodium ions rapidly and reversibly through surface adsorption and surface redox reactions. (C) 2012 Elsevier Ltd. All rights reserved.
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