期刊
CARBON
卷 61, 期 -, 页码 525-536出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2013.04.107
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资金
- EPSRC Grant Supergen Energy Storage [EP/H019596/1]
- Royal Society
- European Research Council [ERC-2009-StG-240500]
- EPSRC [EP/H019596/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H019596/1] Funding Source: researchfish
Spray deposited single-wall carbon nanotube (SWCNT) film electrodes comprising a randomly interconnected meso-porous network with high electrical conductivity and ionic mobility when immersed in an electrolyte have been investigated for applications in electrochemical capacitors. Layer-by-layer (LbL) spray deposition assembly of functionalised, oppositely charged (carboxylic COO- or amine NH3+) SWCNTs has been used to control the density and structure of sprayed electrodes, followed by vacuum and hydrogen heat treatment, and their electrochemical performance as a supercapacitor electrode assessed. Sprayed LbL SWCNT electrodes had faster charging and discharging kinetics than SWCNT-COOH electrodes, with a capacitance of 94 F g(-1) compared with 63 F g(-1) at 2 mV s(-1) in a 1 M H2SO4 electrolyte; and LbL electrode capacitance was maintained to 91 F g(-1) at 200 mV s(-1). The capacitance of LbL SWCNT electrodes increased to 151 F g(-1) at 2 mV s(-1) after vacuum and H-2 heat treatment that removed NH2 and COOH functional groups, and resulted in a hybrid microstructure of SWCNTs and multi-layer graphene sheets from unzipped SWCNTs. (C) 2013 Elsevier Ltd. All rights reserved.
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