期刊
CARBON
卷 62, 期 -, 页码 51-60出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2013.05.051
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资金
- Natural Science Foundation of China [81171453]
- Fundamental Research Funds for the Central Universities
- Program for New Century Excellent Talents in University
- Ministry of Education
- Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
Few-layer graphene prepared from graphite exfoliated by chitosan has a preserved structure without oxidation or destruction of the sp(2) character of the carbon plane and exhibits a higher peroxidase catalytic activity than that of graphene oxide (GO) and its reduced form. The peroxidase catalytic activity of as-obtained few-layer graphene is 45 times higher than that of GO and 4 times higher than that of reduced GO with the same concentration of 30 mu g mL(-1) and the detection limit of hydrogen peroxide is 10 nM. The excellently catalytic performance can be attributed to the fast electron transfer on the surface of few-layer graphene, which is further confirmed by electrochemical characterization. The as-prepared few-layer graphene has been used to determine hydrogen peroxide in three real water samples with satisfactory results. (c) 2013 Elsevier Ltd. All rights reserved.
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