期刊
CARBON
卷 51, 期 -, 页码 381-389出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2012.08.070
关键词
-
资金
- National Basic Research Program of China (973 Program) [2011CB605803, 2011CB605604]
- National Natural Science Foundation of China [50921004]
Unidirectional carbon/carbon (C/C) composites were fabricated by catalytic chemical vapor infiltration, using electroless Ni-P as catalyst. Transmission electron microscopy (TEM) investigations indicate that the catalyst particles (100-800 nm) in the pyrocarbon (PyC) matrix are composed of Ni3P and Ni phases, but only the Ni3P phase was observed in the tiny catalyst particles (<50 nm) in carbon fibers. The catalyst particles in the matrix were encapsulated by high-textured PyC shells, in which openings were observed. The thicknesses of the medium-textured PyC in the composites (720-850 nm) are greater than in conventional C/C composites (660-740 nm), but have no significant difference in texture degree. Catalysts were partially extruded out of the PyC shells and migrated into the carbon fibers, leading to the catalytic graphitization of the carbon fibers, and their structural homogeneity was destroyed. Based on the TEM observation, a dissolution/precipitation mechanism was proposed for the catalytic graphitization of carbon fibers, and a dissolution/precipitation/encapsulation/fracture/extrusion mechanism was proposed for the encapsulation of catalyst particles. (C) 2012 Elsevier Ltd. All rights reserved.
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