期刊
CARBON
卷 50, 期 6, 页码 2287-2295出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2012.01.048
关键词
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资金
- National Natural Science Foundation of China [21174033]
- Fundamental Research Funds for the Central Universities [HIT. NSRIF. 2009086, 2009082]
- State Key Laboratory of Supramolecular Structure and Materials [SKLSSM201111]
Core/shell materials with a movable Fe3O4 core and a carbon shell were prepared using polypyrrole as carbon precursor. They are good candidates as metal catalyst supports due to their magnetic property and large surface area. The outer carbon shell thickness could be well-controlled. In addition, the Fe3O4@C materials displayed good resistance to acids, which would greatly extend their range of use. Because nitrogen atoms originating from pyrrole rings still remained in the carbon shell after calcination, Pd nanoparticles could be anchored on the surface without aggregation. The Fe3O4@C/Pd materials showed excellent catalytic performance in the reduction of methylene blue with sodium borohydride as reducing agent. The catalysts could be easily recycled by an external magnetic field and reused without obvious activity loss. (C) 2012 Elsevier Ltd. All rights reserved.
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