期刊
CARBON
卷 50, 期 2, 页码 727-733出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2011.09.040
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资金
- Australian Research Council (ARC) [DP1093855]
- National Research Foundation of Korea [R32-2008-000-20093-0]
- National Research Foundation of Korea [R32-2012-000-20093-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Graphene nanosheets have been investigated as cathode catalysts for lithium-air batteries with alkyl carbonate electrolyte. Field emission scanning electron microscopy, transmission electron microscope and Raman spectroscopy have confirmed the high quality of the as-prepared graphene nanosheets and the surface analysis has identified the mesoporous characteristic of graphene nanosheets. The electrochemical properties of graphene nanosheets as cathode catalysts in lithium-air batteries were evaluated by a galvanostatic charge/discharge testing. The reaction products on the graphene nanosheets cathode were analyzed by X-ray diffraction and Fourier transform infrared spectroscopy. The graphene nanosheet electrodes exhibited a much better cycling stability and lower overpotential than that of the Vulcan XC-72 carbon. This work demonstrated that graphene nanosheets could be an efficient catalyst for lithium-air batteries. (C) 2011 Elsevier Ltd. All rights reserved.
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