期刊
CARBON
卷 49, 期 13, 页码 4571-4579出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2011.06.070
关键词
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A method is reported that involves the bulk polymerization of styrene monomer in the presence of multi-wall carbon nanotubes (MWCNTs) and polystyrene (PS) beads, for the preparation of MWCNT/PS conducting composites with a significantly lower (0.08 wt.% MWCNT) percolation threshold than previously reported. Thus, the conductivities of 7.62 x 10(-5) and 1.48 x 10(-3) S cm(-1) were achieved in the MWCNT/PS composites through homogeneous dispersion of 0.08 and 0.26 wt.% CNTs, respectively in the in situ polymerized PS region by using 70 wt.% PS beads during the polymerization. The extent of dispersion and location of the MWCNTs in the PS matrix has been investigated with a scanning and transmission electron microscopy. The conductivity of the composites was increased with increasing wt.% of the PS beads at a constant CNT loading, indicating the formation of a more continuous network structure of the CNTs in PS matrix. (C) 2011 Elsevier Ltd. All rights reserved.
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