期刊
CARBON
卷 48, 期 15, 页码 4276-4282出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2010.07.037
关键词
-
资金
- High-Performance Materials Institute (HPMI) at Florida State University
- NSF [DMR-0602859, DMR-0654118]
- State of Florida
- DOE
Carbon/carbon composites consisting of single-walled carbon nanotube (SWCNT) buckypaper (BP) and mesophase pitch resin have been produced through impregnation of BP with pitch using toluene as a solvent. Drying, stabilization and carbonization processes were performed sequentially, and repeated to increase the pitch content. Voids in the carbon/carbon composite samples decreased with increasing impregnation process cycles. Electrical conductivity and density of the composites increased with carbonization by two to three times that of pristine BP. These results indicate that discontinuity and intertube contact barriers of SWCNTs in the BP are partially overcome by the carbonization process of pitch. The temperature dependence of the Raman shift shows that mechanical strain is increased since carbonized pitch matrix surrounds the nanotubes. (C) 2010 Elsevier Ltd. All rights reserved.
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