期刊
CARBON
卷 48, 期 3, 页码 844-853出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2009.10.038
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资金
- NSF [DMR-0117792, ECCS-0925708, NSFECCS-0925682]
- Interconnect Focus Center New York at RPI
- Directorate For Engineering
- Div Of Electrical, Commun & Cyber Sys [0925682] Funding Source: National Science Foundation
We present a detailed investigation of the formation of stable catalyst particles on Inconel substrates, an important step in the growth mechanism of carbon nanotubes on these substrates. The chemical nature of the interaction of catalyst and substrate was investigated using XPS, high-resolution cross-sectional TEM, and EDS studies. The results indicate that Cr2O3, an electrically conductive oxide, plays an important role in stabilizing nanoclusters of Fe catalyst under typical growth conditions. The nature of growth on a number of other superalloys is also presented and is examined with respect to their chemical composition. (C) 2009 Elsevier Ltd. All rights reserved.
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