Formylation of single-walled carbon nanotubes

Formyl or aldehyde groups are transferred to the surface of single-walled carbon nanotubes (SWCNTs) by reaction of reduced carbon nanotubes with N-formylpiperidine. This could open the way for more versatile chemical modification reactions of carbon nanotubes than is currently possible using functionalization methods reported to date. The formylated SWCNTs were characterized by thermogravimetric analysis-mass spectrometry and Raman, UV-vis-NIR and FTIR spectroscopy. The location and distribution of the functional groups was determined by AFM using electrostatic interactions with gold nanoparticles. The formylated SWCNTs were further derivatized with a fluorescent dye and studied using fluorescence spectroscopy. (C) 2010 Elsevier Ltd. All rights reserved.