期刊
CARBON
卷 47, 期 7, 页码 1715-1722出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2009.02.024
关键词
-
资金
- Shandong Province [Y2007B29, Y2008F36, 2008BS09007]
- Shandong University of Technology [2006KJM17]
A series of hierarchical porous carbons (HPCs) were prepared by a combination of self-assembly and chemical activation. Pore-structure analysis shows that micropores can be generated within the mesopore wall of mesoporous carbon in a controllable manner during activation. As evidenced by cyclic voltammetry, galvanostatic charge/discharge cyclings and frequency response measurements, HPCs show superior capacitive performances to hard-templated ordered mesoporous carbons, which can be attributed to the generated pore surfaces that play most important role in the formation of double-layer capacitance and to their unique hierarchical porous structure that favors the fast diffusion of electrolyte ions into the pores. Of special interest is the fact that HPCs maintains 180 F/g at high-frequency of 1 Hz. (C) 2009 Elsevier Ltd. All rights reserved.
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