期刊
CARBOHYDRATE RESEARCH
卷 344, 期 1, 页码 29-35出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2008.09.016
关键词
Candida guilliermondii; Mannan; Oligomannosides; Neoglycoconjugates; Synthesis
The 3-aminopropyl glycoside of a heptasaccharide fragment of the cell wall mannan from Candida guilliermondii 18, which corresponds to the antigenic Factor 9, has been synthesized by a convergent approach based on glycosylation of a tetrasaccharide acceptor with a trisaccharide donor as the key step to give a protected heptasaccharide 17. Subsequent two-step deprotection of 17 afforded the heptamannoside 18, which was then Conjugated with BSA using the squarate procedure. (C) 2008 Elsevier Ltd. All rights reserved.
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