期刊
CARBOHYDRATE RESEARCH
卷 344, 期 17, 页码 2388-2393出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2009.08.036
关键词
Powder X-ray diffraction; Isothermal titration calorimetry; Association constant; Cyclodextrins; Metobromuron
资金
- National Research Foundation [67381]
- CONICET
- FONCYT
- MINCyT-Cordoba (Argentina)
- National University of Cordoba
- NRF (South Africa)
- MINCyT (Argentina)
- YPF Foundation (Argentina)
- Korea Agency for Infrastructure Technology Advancement (KAIA) [67381] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
We report the formation of inclusion complexes between the phenylurea herbicide metobromuron [3-(p-bromophenyl)-1-methoxy-1-methylurea] and beta- and gamma-cyclodextrin in the solid state. Formation of crystalline inclusion complexes by the kneading method was confirmed by powder X-ray diffraction and further structural characterization using the principles of isostructurality followed. In addition, Delta H degrees, Delta S degrees, Delta G degrees and the association constants (K) at 298 K were determined for complex formation in solution using isothermal titration calorimetry. The magnitudes of K for the formation of 1:1 complexes between metobromuron and alpha-, beta- and gamma-CD were estimated as 598, 310 and 114, respectively. (C) 2009 Elsevier Ltd. All rights reserved.
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