Lead removal onto cross-linked low molecular weight chitosan pyruvic acid derivatives

Adsorption capacity of cross-linked low molecular weight chitosan pyruvic acid derivatives CS(n)PA-GLA (n = 8, 11) were examined by employing 2(3) factorial design method. Three (3) factors and two (2) levels of adsorbent dose (A) (0.05 and 0.1 g), adsorbent type (B) (CS(8)PA-GLA and CS(11)PA-GLA) and concentration of lead solution (C) (1 and 3 mg/L) were considered. From the statistical analysis, all the main parameters (A, B and C) and some interactions of the main parameters (AC and ABC) had influence on the adsorption process at 5% significance level. The adsorption process was greatly influenced by the adsorbent type (B). The adsorption equilibrium results correlated well with the Freundlich isotherm model. The adsorption kinetic data also correlated well with the pseudo second order. The thermodynamic studies also revealed that the nature of lead adsorption was spontaneous and endothermic. The findings suggest that CS(8)PA-GLA is better than CS(11)PA-GLA for lead sorption. (C) 2014 Published by Elsevier Ltd.