Biosorption of Cu2+, Pb2+ and Cr6+ by a novel exopolysaccharide from Arthrobacter ps-5

The biosorption behaviors and mechanisms for Cu2+, Pb2+ and Cr6+ by a novel exopolysaccharide (EPS) from Arthrobacter ps-5 have been studied in the paper. The influences of EPS concentration, solution pH and ionic strength on adsorption property were investigated. The EPS showed strong biosorption capability, up to 169.15 mg/g of Cu2+, 216.09 mg/g of Pb2+ and 84.47 mg/g of Cr6+, respectively. With the additional concentration of Ca2+ and K+ increased, the biosorption ability on Cu2+, Pb2+ and Cr6+ decreased significantly and followed the order of K+ < Ca2+. Infrared spectrometry analysis demonstrated that the groups of O-H, C=O, C-O-C and C=O-C of the EPS involved in metal biosorption process were the main functional groups for binding metal ions. (C) 2013 Elsevier Ltd. All rights reserved.