4.7 Article

Preparation of cellulose derived from corn stalk and its application for cadmium ion adsorption from aqueous solution

期刊

CARBOHYDRATE POLYMERS
卷 90, 期 2, 页码 1008-1015

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2012.06.035

关键词

Cellulose; Corn stalk; Isolation; Modification; Adsorption

资金

  1. National Natural Science Foundation of China [40730741, 41073088]
  2. Hi-Tech Research and Development Program of China [2007AA061001]
  3. National Special Science and Technology Project on Treatment and Control of Water pollution of China [2008ZX07211-001]
  4. Open Foundation of the State Key Laboratory of Pulp and Paper Engineering in South China University of Technology
  5. Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, China

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Cellulose was isolated from corn stalk and modified by graft copolymerization to produce an absorbent material (AGCS-cell), which was characterized by scanning electron microscope and energy disperse spectroscopy (SEM-EDS), X-ray diffraction (XRD) and solid-state CP/MAS C-13 NMR. The results showed that AGCS-cell had better adsorption potential for cadmium ion than unmodified cellulose because of the addition of functional groups (-CN and -OH groups) and the lower crystallinity. The Langmuir isotherms gave the best fit to the data and gave an adsorption capacity was 21.37 mg g(-1), which was close to unpurified cellulose (AGCS) and reflected the feasibility of using AGCS-cell as an adsorbent to remove cadmium ions. (C) 2012 Elsevier Ltd. All rights reserved.

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