Synthesis, characterization and swelling behaviors of sodium alginate-g-poly(acrylic acid)/sodium humate superabsorbent

A novel sodium alginate-g-poly(acrylic acid)/sodium humate superabsorbent was prepared by graft copolymerization with sodium alginate, acrylic acid and sodium humate in aqueous solution, using N,N'-methylenebisacrylamide as a crosslinker and ammonium persulfate as an initiator. The effects of crosslinker, sodium alginate and sodium humate content on water absorbency of the superabsorbent were studied. The swelling behavior in solutions of various pH and the swelling kinetics in saline solutions (5 mmol/L NaCl and CaCl2) were also investigated. The results from IR analysis showed that both sodium alginate and sodium humate react with the acrylic acid monomer during the polymerization process. The introduction of sodium humate into the sodium alginate-g-poly(acrylic acid) system could enhance the water absorbency and the superabsorbent containing 10 wt% sodium humate acquired the highest water absorbency (1380 g/g in distilled water and 83 g/g in 0.9 wt% NaCl solution). (C) 2008 Elsevier Ltd. All rights reserved.