期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 13, 页码 1743-1745出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b418302a
关键词
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Alkoxide-functionalised N-heterocyclic carbenes (NHCs) stabilise the potassium-imidazole-2-ylidene fragment against 1,2 alkyl rearrangement reactions; this allows the first structural characterisation of a potassium NHC complex, which reveals distorted and unusual bonding interactions between the imidazole ring and the potassium cation.
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