期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 10, 页码 1243-1254出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b416425c
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This article describes recent achievements made by us and other groups in targeted synthesis of porphyrin-based framework solids by various non-covalent mechanisms of molecular recognition. The self-assembly processes are effected in a tunable manner either by direct association of suitably designed porphyrin building blocks, or by their supramolecular aggregation through external linkers as metal ions and organic bi-dentate ligands. Many of these crystalline porphyrin materials exhibit open architectures and remarkable structural integrity, and their potential application for selective guest storage and molecular sieving is highlighted.
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