期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 32, 页码 4119-4121出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b508069j
关键词
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The reaction of readily available 1-substituted 2,3-allenols with Br-2, NBS, or I-2 afforded the not-easily-available but synthetically useful 3-halo-3-alkenals or 2-halo-2-alkenyl ketones in good yields via a sequential electrophilic interaction of X+ with the allene moiety, a 1,2-aryl or proton shift, and a H+-elimination process; the structures of the products were established by X-ray diffraction study.
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