期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 21, 页码 2716-2718出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b501964h
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Tin chlorides, SnCl2 and SnCl4 center dot 5H(2)O are excellent catalysts for the reactions of trioses, dihydroxyacetone and glyceraldehyde with alcohols (MeOH, EtOH and nBuOH) to give alkyl lactates, whose reaction mechanism involves the intermediary formation of pyruvic aldehyde followed by its esterification, which is distinctively promoted by tin halides.
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