期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 43, 页码 5390-5392出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b510996e
关键词
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Tungsten complex 5 with a coordinated 2-azidoethyl isocyanide ligand reacts with PMe3 at the azido function to give a complex with a coordinated iminophosphorane which upon hydrolysis of the P=N bond yields a complex with an NH,NH-stabilized N-heterocyclic carbene ligand, 7; alkylation of the carbene ring nitrogen atoms gives a complex with an N,N'-dialkylated imidazolidin-2-ylidene ligand, 8.
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