Effect of NOM, turbidity and floc size on the PAC adsorption of MIB during alum coagulation

The effect of natural organic material (NOM) and turbidity on the powdered activated carbon (PAC) adsorption of the odour compound 2-methylisoborneol (MIB) was evaluated during alum coagulation. The character of the floes, in terms of their size and fractal dimensions (D-f), was used to interpret the observed adsorption behaviour of MIB during the coagulation process. As the alum dose was increased, the adsorption of MIB decreased. This was determined to be due to the size of the floes, with larger floes incorporating PAC into their structure, reducing the efficiency of mixing, and the bulk diffusion kinetics for the MIB molecule. The presence of turbidity also reduced MIB adsorption due to the formation of larger floes. The character of NOM was found to have a greater influence on the adsorption of MIB than the floc structure. (c) 2005 Elsevier Ltd. All rights reserved.