期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 3, 期 24, 页码 4395-4401出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b513397a
关键词
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The Diels-Alder cycloadditions of the alpha-acetoxynitroso dienophile 1 in water are reported. The rapid and high yielding synthesis of structurally diverse 3,6-dihydro-1,2-oxazines complements the straightforward elaboration of aminoalcohols obtained from the alpha-acetoxynitroso derivative 1 in anhydrous medium. A rationale for this solvent-dependent product distribution is proposed.
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