期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 11, 期 1, 页码 288-297出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200400672
关键词
C-C bond formation; heterogeneous catalysis; Lewis acids; montmorillonite
Montmorillonite-enwrapped copper and scandium catalysts (Cu2+- and Sc3+-monts) were easily prepared by treating Na+-mont with the aqueous solution of the copper nitrate and scandium triflate, respectively. The resulting Cu2+- and Sc3+-monts showed outstanding catalytic activities for a variety of carbon-carbon bond-forming reactions, such as the Michael reaction, the Sakurai-Hosomi allylation, and the Diels-Alder reaction, under solvent-free or aqueous conditions. The remarkable activity of the mont catalysts is attributable to the negatively charged silicate layers that are capable of stabilizing metal cations. Furthermore, these catalysts were reusable without any appreciable loss in activity and selectivity. The Cu2+-mont-catalyzed Michael reaction proceeds via a ternary complex in which both the 1,3-dicarbonyl compound and the enone are coordinated to a Lewis acid Cu2+ center.
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