Solvothermal reaction of CuI with flexible 1,3-bis(4-pyridyl) propane generated the first three-dimensional coordination polymer constructed with the rigid tetrahedrally connected Cu4I4 cluster unit. The net is a rare chiral triple-interpenetrated, quartz net with of vertex symbol 6(4).8(2). The solid-state luminescence spectrum displays a strong red emission band at room temperature (lambda(max) = 601 nm), characteristic of the Cu I cluster centers.
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