期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 15, 期 37, 页码 4020-4024出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b507875j
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Experimental observations on the B-4 phase of liquid crystal mixtures formed from bent-core (P-8-O-PIMB) and rod (5CB) achiral molecules reveal the stabilization of the B-4 phase with an unusually large size of chiral domains. The phenomenon is interpreted as an intrinsic property of the B-4 phase when arising below the isotropic liquid (Iso); actually direct transition between Iso and B-4 phases occurs except for only very limited regions of pure P-8-O-PIMB and 5CB molecules. The phase diagram of the mixture shows the existence of a new phase, closely related to the B-4 phase.
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