期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 3, 期 11, 页码 2140-2144出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b503862f
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资金
- NINDS NIH HHS [NS38049] Funding Source: Medline
- NATIONAL INSTITUTE OF NEUROLOGICAL DISORDERS AND STROKE [R01NS038049] Funding Source: NIH RePORTER
Total syntheses of indoloquinolizidine alkaloid (+/-)-, R-(+)-, and S-(-)-deplancheine are described here. The synthesis features an enantioselective intramolecular formal aza-[3 + 3] cycloaddition for the construction of the quinolizidine CD-ring. This application serves to introduce a new synthetic strategy for the synthesis of indoloquinolizidine alkaloids.
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