A fixed-bed column for phosphate removal from aqueous solutions using an andosol-bagasse mixture

It is difficult to eliminate phosphate from large volumes of water in batch mode using an adsorbent such as andosol. In a fixed-bed column, andosol has a very low permeability. In this study, andosol was mixed with bagasse to increase permeability. The mixture was then applied for the adsorption of phosphate in a fixed-bed column. Optimum and stable permeability was obtained with a 50/50 mixture of andosol and bagasse. The maximum adsorption capacity obtained was 4.18 mg/g for a column with a bed depth of 1.8 cm and a flow rate of 4 mL/min. The experimental data fit best to Thomas and Adam-Bohart models. These experimental results were applied in the treatment of natural phosphate-containing water from Yaounde Municipal Lake in Cameroon. Column performance increased by 60% due to the presence of Ca2+ and Mg2+ in the natural water. These cations form complexes with phosphate at the andosol surface. The standard enthalpy 15.964 kj/mol indicated that phosphate adsorption on andosol-bagasse mixture was an endothermic process. Kinetic experiments demonstrated that phosphate adsorption fitted better with a pseudo-second-order model. (C) 2014 Elsevier Ltd. All rights reserved.