期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 347, 期 1, 页码 45-49出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200404224
关键词
cyclic alkene; dioxygen; epoxidation; manganese complex; N,O ligands
The highly efficient oxidation of cyclic alkenes was realized using a novel manganese complex as catalyst and molecular oxygen as oxidant in the presence of isobutyraldehyde. The reaction of 2-pyridinecarboxylic acid with p-toluidine gave the corresponding amide in good yield. A manganese complex bearing this ligand was highly active in isobutyraldehyde-mediated epoxidation of cyclic alkenes using molecular oxygen as oxidant, and up to and over 99.9% conversion of the substrate and 99% yield of the epoxide were obtained for the epoxidation of norbornylene.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据