期刊
ARKIVOC
卷 -, 期 -, 页码 39-48出版社
ARKAT USA INC
DOI: 10.3998/ark.5550190.0006.e05
关键词
N-heterocyclic carbene; L-proline; chiral; arylboronic acid; aldehyde
Novel chiral imidazolium salts and a stable N-heterocyclic carbene-Rh complex derived from L-proline have been synthesized. The N-heterocyclic carbene-Rh complexes either generated in situ or pre-synthesized are active catalysts for the addition reaction of arylboronic acids to aldehydes affording the corresponding secondary alcohols in excellent yields.
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