期刊
MATERIALS SCIENCE AND TECHNOLOGY
卷 22, 期 6, 页码 719-724出版社
TAYLOR & FRANCIS LTD
DOI: 10.1179/174328406X101328
关键词
dielectric; ceramic; conductivity; permittivity; networks; composite
The frequency dependent conductivity and permittivity of a ceramic composite are modelled using electrical networks consisting of randomly positioned resistors and capacitors. The electrical network represents a heterogeneous microstructure that contains both insulating ( the capacitor) and conductive regions ( the resistor). To validate model results, a model ceramic conductor - insulator composite was designed consisting of a porous lead zirconate titanate impregnated with different concentrations of water. Excellent agreement between experimental and model data was achieved with a strong correlation with many other ceramics, glasses and composites. It is proposed that the 'universal' dielectric response of many materials is a consequence of microstructural heterogeneity. The modelling approach could be used as a simple and effective method for microstructural design of ceramics and other materials with tailored dielectric properties.
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