期刊
ZEITSCHRIFT FUR KRISTALLOGRAPHIE
卷 221, 期 5-7, 页码 477-481出版社
WALTER DE GRUYTER GMBH
DOI: 10.1524/zkri.2006.221.5-7.477
关键词
iron borides; metal flux; high pressure; single crystal structures analysis; X-ray diffraction
Crystals of the iron borides FeB and Fe2B were obtained from two different high temperature synthesis routes, viz. in combined copper/gallium flux and under high pressure conditions. Their crystal structures were investigated at room and low temperatures. Structure models from the literature were confirmed. The position of the boron atoms was unambiguously determined. FeB (Pnma, no. 62) contains zig-zag chains of boron atoms in which the boron atoms are coordinated by seven iron atoms in the form of a mono-capped trigonal prism. Fe2B (I4/mcm, no. 140) contains single boron atoms in a square antiprismatic iron atom coordination.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据