期刊
COORDINATION CHEMISTRY REVIEWS
卷 250, 期 11-12, 页码 1391-1418出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2005.12.018
关键词
polyethylene; 2,6-bis(iminopyridyl) ligands; iron; cobalt; catalysis
In this review are highlighted the key advances that have occurred in the discovery and development of 2,6-bis(imino)pyridyl iron(II) and cobalt(II) catalysts for the transformation of ethylene into linear and branched homopolymers or into alpha-olefins with either Schulz-Flory or Poisson distribution. Particular attention has been paid to studies of the electronic and geometrical structure of both supporting ligands and metal complexes as well as to the mechanisms of precatalyst activation, chain-propagation and chain-transfer. (c) 2005 Elsevier B.V. All rights reserved.
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