期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 10, 期 8, 页码 1007-1016出版社
WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424606000351
关键词
porphyrins; rhodanine acetic acid; dyads; solar cells
A series of four new porphyrin-rhodanine dyads were synthesized having the rhodanine acetic acid group either at the meso- or the pyrrole-beta position of a free-base/zinc porphyrin. These dyads were fully characterized by UV-visible, H-1 NMR, MALDI-MS and fluorescence spectroscopies and cyclic voltammetry. Both the Soret and Q-bands were red-shifted in the case of pyrrole(3 substituted dyads. The redox potentials of all four dyads were altered in comparison with their individual constituents. The dyads were tested in dye sensitized solar cells and the zinc metalated dyads gave a better performance in comparison with the corresponding free-base dyads. Copyright (c) 2006 Society of Porphyrins & Phthalocyanines.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据