期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 10, 期 8, 页码 1071-1079出版社
WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424606000430
关键词
cardanol,3-n-pentadecylphenol; porphyrins; metalloporphyrins; epoxy
This paper deals with the synthesis of a new hybrid meso-tetraarylporphyrin-cardanol with the cardanol bearing an unsaturated chain. Cardanol is a renewable, natural, widely available and relatively low-cost material obtained as a by-product of the cashew industry which provides cashew kernels for edible use. The unsaturation in the chain in the new hybrid meso-tetraaryiporphyrin-cardanol leads to chemical and physico-chemical properties which are different from the saturated derivatives. The unsaturation also allows preparation of the corresponding epoxy compounds as well as self-metathesis derivatives. Copyright (c) 2006 Society of Porphyrins & Phthalocyanines.
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