期刊
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
卷 10, 期 7, 页码 942-947出版社
SOC PORPHYRINS & PHTHALOCYANINES
DOI: 10.1142/S1088424606000260
关键词
porphyrin; catalysis; oxidation; hydrocarbon; styrene; benzaldehyde; air
The aerobic oxidative cleavage of styrene C=C double bonds catalyzed by simple manganese porphyrin is reported. Under the catalysis of chloro(tetraphenylporphinato) manganese, the oxidative cleavage of the carbon-carbon double bond of the styrene with air yields benzaldehyde. Our results show that the oxidative cleavage and the epoxidation of the styrene double bond are the competition reactions in the styrene-manganese porphyrin-air system. The reaction temperature decided the product distribution. Under the conditions of 0.4 MPa. air and 30 ppm of chloro(tetraphenylporphinato)manganese, the styrene conversion was 20.0% and the selectivity of benzaldehyde and styrene oxide was 81.7% and 12.7% respectively when the reaction temperature was 110 degrees C. Styrene conversion was 92.5% and the selectivity of benzaldehyde and styrene oxide was 48.1% and 41.2% respectively when the reaction temperature was 120 degrees C. Copyright (c) 2006 Society of Porphyrins & Phthalocyanines.
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