期刊
CHEMICAL RECORD
卷 6, 期 3, 页码 117-132出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.20077
关键词
palladacycle; oxime; nanoparticles; catalysis; cross coupling
Our review critically presents the main achievements, advantages, and limitations of oxime palladacycles as high-turnover catalysts for Heck, as well as homo- and cross-coupling reactions such as Suzuki-Miyaura, Stille, Ullmann-type, Cassar-Heck-Sonogashira, sila-Sonogashira, Glaser-type, Hiyama, and alkoxycarbonylation reactions. New developments in this area are reviewed from a mechanistic and synthetic point of view. The role of oxime palladacycles as a source of highly active zero-valent palladium species is also discussed. (c) 2006 The Japan Chemical journal Forum and Wiley Periodicals, Inc.
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