期刊
ANALYTICAL METHODS
卷 7, 期 6, 页码 2800-2805出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ay02894e
关键词
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资金
- Anhui Province College Natural Science Foundation [KJ2013A065]
- Anhui Province Key Laboratory of Environment-friendly Polymer Materials Research Fund [KF2012003]
- National College Students' Innovation and Entrepreneurship Training Plan Project [201410878065]
A novel anionic water-soluble poly(3,4-propylenedioxythiophene) derivative (WSPProDOT) has been prepared through FeCl3 oxidative polymerization with a subsequent post-polymerization defunctionalization process, and applied as a colorimetric sensor to determine and discriminate non-ionic and cationic surfactants in aqueous solutions. The de-aggregation, conformation change of WSPProDOT and its colorimetric and fluorescent responses toward non-ionic and cationic surfactants have been studied by absorption and emission spectroscopy. The solution color of WSPProDOT changes from purple to blue upon addition of a non-ionic surfactant and from purple to black for a cationic surfactant. Therefore, non-ionic and cationic surfactants can be discriminated and detected using this versatile sensing platform.
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