期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 29, 页码 3045-3062出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b602237e
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Throughout history symmetry and chirality have inspired artists and scientists alike. Given that rotational axes are the only elements of symmetry compatible with chirality, it is not surprising that C-2- and C-3-symmetrical molecules have attracted considerable attention. In recent years, the aesthetic appeal of C-2- symmetrical molecules has been translated into many widely-used applications some of which are of commercial importance by its exploitation in the area of asymmetric catalysis. In contrast, exploitation of the arguably greater aesthetic appeal of C-3-symmetric molecules is still in its infancy. This review, which surveys the applications of chiral C-3-symmetrical molecules in the areas of asymmetric catalysis, molecular recognition and nanoarchitecture, has been designed with a view to identifying some of the most promising areas of application of these very beautiful molecules.
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