期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 23, 页码 2480-2482出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b603985e
关键词
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Hexagon-shaped [6+6] Schiff-base macrocycles with 12 imine bonds are reported. These giant macrocycles possess 6 N2O2 coordination environments and mass spectrometry evidence for hexametallation of one macrocycle is provided. Semi-empirical calculations reveal two stable conformations with boat and chair geometries for the macrocycles metallated with Ni(II), analogous to the conformations observed for cyclohexane.
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