期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 46, 页码 4841-4843出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b608481h
关键词
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Chiral C-2-symmetric quaterpyridine L reacts with [Pd(eta(3)-C3H5)Cl](2) to form a chiral single-stranded helical binuclear palladium complex of formula [Pd-2(eta(3)-C3H5)(2)(L)](2+); the complex can efficiently catalyze allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate with enantioselectivity up to 85%.
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