期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 11, 页码 1191-1193出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b515725k
关键词
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A highly enantioselective Mannich reaction between malonate esters and N-Boc and N-Cbz aldimines, catalysed by a bifunctional cinchonine derivative, has been developed; extension of this methodology to encompass the use of 2-substituted-1,3-dicarbonyl nucleophiles allows the formation of adjacent stereocentres, one of which is quaternary, in high relative and absolute stereocontrol.
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