Two novel 3D coordination polymers, Cd(CTC)(H2O)center dot (H2PIP)(0.5)(H2O) (1) with zeolite ABW topology and Cd(CTC)center dot(HIPA) (2) with zeolite BCT topology, have been synthesized by constructing inorganic and organic 4-connected building units and using the organic bases as templates, and the frameworks of 1 and 2 not only expand the original structures of zeolites ABW and BCT, but also exhibit significant advantages over them in terms of thermal stability, ion exchange and adsorption.
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