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Anisotropic behavior of knight shift in superconducting state of NaxCoO2 center dot yH(2)O

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PHYSICAL SOC JAPAN
DOI: 10.1143/JPSJ.75.013708

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superconductivity; hydrate sodium cobalt oxide; NMR; spin fluctuations

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The Co Knight shift was measured in an aligned powder sample of NaxCoO2 center dot yH(2)O, which shows superconductivity at T-c similar to 4.6 K. The Knight-shift components parallel (K-c) and perpendicular to the c-axis (along the ab plane K-ab) were measured in both the normal and superconducting (SC) states. The temperature dependences of K-ab and K-c are scaled with the bulk susceptibility, which shows that the microscopic susceptibility deduced from the Knight shift is related to Co-3d spins. In the SC state, the Knight shift shows an anisotropic temperature dependence: K-ab decreases below 5 K, whereas K-c does not decrease within experimental accuracy. This result raises the possibility that spin-triplet superconductivity with the spin component of the pairs directed along the c-axis is realized in NaxCoO2 center dot yH(2)O.

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