期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 4, 期 24, 页码 4440-4443出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b613331b
关键词
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We report the first catalytic Sakurai reaction of N-alkoxy-carbonylamino sulfones with allylsilanes. The allylation reaction of N-alkoxycarbonylamino phenylsulfones with allyltrimethylsilane proceeded smoothly with low catalyst loading of bismuth triflate (2.0 mol%) to afford the corresponding protected homoallylic amines in moderate to very good yields ( up to 96%).
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