期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 4, 期 7, 页码 1195-1201出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b600056h
关键词
-
资金
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM061066] Funding Source: NIH RePORTER
- NIGMS NIH HHS [GM-61066] Funding Source: Medline
Electrostatic effects exert strongly stabilizing influences on cations, in many cases controlling the conformational preferences of these cations. The lowest energy conformers are ones where the positive charge is brought closest to substituents bearing partial negative charges. These conformational biases, along with stereoelectronic effects, can control the stereoselectivity of reactions involving carbocationic intermediates.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据