期刊
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
卷 447, 期 -, 页码 533-540出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/15421400500377214
关键词
chemical synthesis; dodecylbenzene sulphonic acid; polyaniline
An investigation of the synthesis parameters (i.e., temperature and acid concentrations) in the chemical preparation of PAni-DBSA, was performed. The synthesis temperature was varied from 0 degrees to 40 degrees C, producing a strong effect on both the oxidation states during chain propagation stage and properties of polymers. DBSA molecules are incorporated in the PAni chain. The synthesis temperature has a strong influence on the properties of PAni-DBSA. PAni with a needle-like structure and compact morphology was obtained. The conductivity of polymers is dependent on the benzenoid/quinoid ratio in the polymer chain.
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