期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 9, 期 1, 页码 68-71出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2005.10.004
关键词
ruthenium complexes; 2,2': 6',2-terpyridine; thenyloxy-2,2': 6',2-terpyridine; electropolymerisation
Two ligands whose general formula is R-terpy with terpy = 2,2':6',2-terpyridine bearing at the 4-position a substituent R = 2-thenyloxy and 3-thenyloxy were synthesised. The electronic spectra and the electrochemical behaviour of the corresponding Ru(II) complexes were investigated. The donor effect of the grafted groups as the non-conjugation between the pi* ligand orbitals of the terpyridine and the thienyl groups induce an increase of the energy level of the LUMO. (c) 2005 Published by Elsevier B.V.
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